Magneto Seebeck effect in REFeAsO (RE=rare earth) compounds: probing the magnon drag scenario

We investigate Seebeck effect in REFeAsO (RE=rare earth)compounds as a function of temperature and magnetic field up to 30T. The Seebeck curves are characterized by a broad negative bump around 50K, which is sample dependent and strongly enhanced by the application of a magnetic field. A model for the temperature and field dependence of the magnon drag contribution to the Seebeck effect by antiferromagnetic (AFM) spin fluctuation is developed. It accounts for the magnitude and scaling properties of such bump feature in our experimental data. This analysis allows to extract precious information on the coupling between electrons and AFM spin fluctuations in these parent compound systems, with implications on the pairing mechanism of the related superconducting compounds

Self-magnetic compensation and Exchange Bias in ferromagnetic Samarium systems

For Sm(3+) ions in a vast majority of metallic systems, the following interesting scenario has been conjured up for long, namely, a magnetic lattice of tiny self (spin-orbital) compensated 4f-moments exchange coupled (and phase reversed) to the polarization in the conduction band. We report here the identification of a self-compensation behavior in a variety of ferromagnetic Sm intermetallics via the fingerprint of a shift in the magnetic hysteresis (M-H) loop from the origin. Such an attribute, designated as exchange bias in the context of ferromagnetic/antiferromagnetic multilayers, accords these compounds a potential for niche applications in spintronics. We also present results on magnetic compensation behavior on small Gd doping (2.5 atomic percent) in one of the Sm ferromagnets (viz. SmCu(4)Pd). The doped system responds like a pseudo-ferrimagnet and it displays a characteristic left-shifted linear M-H plot for an antiferromagnet.Comment: 7 pages and 7 figure

Critical behavior of the ferromagnetic transition in GdSc(Si,Ge) intermetallic compounds

A complete study on the critical behavior of the paramagnetic to ferromagnetic transition in intermetallics GdScSi, GdScGe, GdSc(Si0.5Ge0.5) and Gd(Sc0.5Ti0.5)Ge has been carried out by means of magnetic as well as calorimetric measurements, using a high resolution ac photopyroelectric technique. The critical exponents alfa, beta, gamma, delta and the ratio of the critical coefficients A+/A- have been independently obtained for the four samples. It has been proved that the magnetic interactions are short range as the values of the critical parameters correspond to the 3D-Heisenberg class, stating an isotropic ordering of the Gd spins. In some cases, there are small deviations of some of the critical parameters from the theoretical values which have been discussed on the basis of the variation of the d states hybridization between the rare earth and the transition metal, as well as the presence of small magnetocrystalline anisotropies arising from spin-orbit coupling effects.This work has been supported by Universidad del País Vasco UPV/EHU (GIU16/93)

Study of the magnetocaloric effect in intermetallics RTX (R = Nd, Gd; T = Sc, Ti ; X = Si, Ge)

A detailed study of the magnetocaloric properties of six compounds of the intermetallic family RTX (R = Nd, Gd; T = Sc, Ti ; X = Si, Ge) has been undertaken: NdScSi, NdScGe, GdScSi, GdScGe, GdSc(Si0.5Ge0.5) and Gd(Sc0.5Ti0.5)Ge. The magnetic entropy changes at the Curie temperature TC and the refrigerant capacities signal that they are competitive magnetocaloric materials, showing that an improvement can be obtained by tuning the composition, as Gd(Sc0.5Ti0.5)Ge presents the best properties. These magnetocaloric variables fulfill the scaling equations with the critical parameters corresponding to the universality classes to which the ferromagnetic transitions belong (3D-XY, 3D-Heisenberg, Mean field). For each compound, a universal curve has been found for the rescaled magnetic entropy changes obtained at different applied fields, whose behavior at temperatures below TC indicate the relevance of taking into account the demagnetization field. Finally, it has been demonstrated that the rescaled magnetic entropy changes for the compounds which share the same universality class collapse onto a single universal curve.This work has been supported by Universidad del País Vasco UPV/EHU (GIU16/93)

Effect of Nd doping on the crystallographic, magnetic and magnetocaloric properties of NdxGd3-xCoNi

The crystal structure, magnetic and magnetocaloric properties, and the critical behavior of representative compounds in the pseudo-ternary NdxGd3-xCoNi series have been investigated (x = 0.15, 0.5, 1.0, 1.5). All these phases are isotypic with the parent compound Gd3CoNi, crystallizing with the monoclinic Dy3Ni2-type (mS20, C2/m, No. 12). All samples present a paramagnetic to ferromagnetic (PM-FM) second order phase transition with decreasing Curie temperature as the Nd concentration is increased (TC = 171 K, 150 K, 120 K and 96 K, respectively) and, at lower temperatures, there is a spin reorientation which leads to a complex magnetic ground state. The critical exponents (beta, gamma, delta) have been retrieved for the PM-FM transitions. On the one hand, in x = 0.15, 0.5, 1.5 the value of γ ≈ 1 indicates that the magnetic interactions are long-range order while the values of β point to a certain deviation from the 3D-Heisenberg universality class; on the other hand, NdGd2CoNi has a particular critical behaviour, as β is close to the Mean Field model while γ is close to the uniaxial 3D-Ising one. Concerning the magnetocaloric properties, the magnetic entropy change and refrigerant capacity present competitive values, interesting for cryogenic applications. Finally, the thermal diffusivity values of these compounds are extremely good for practical magnetocaloric refrigeration systems, as they are in the range 1.5-3 mm2/s.This work has been supported by Departamento de Educación del Gobierno Vasco (Project No. IT1430-22)

Experimental Evidence for Static Charge Density Waves in Iron Oxypnictides

In this Letter we report high-resolution synchrotron x-ray powder diffraction and transmission electron microscope analysis of Mn-substituted LaFeAsO samples, demonstrating that a static incommensurate modulated structure develops across the low-temperature orthorhombic phase, whose modulation wave vector depends on the Mn content. The incommensurate structural distortion is likely originating from a charge-density-wave instability, a periodic modulation of the density of conduction electrons associated with a modulation of the atomic positions. Our results add a new component in the physics of Fe-based superconductors, indicating that the density wave ordering is charge driven

Formation, Stability and Magnetism of New Gd3TAl3Ge2 Quaternary Compounds (T = Mn, Cu)

A study on the formation and stability of new quaternary compounds with the general chemical formula Gd3TAl3Ge2 (T = Mn, Cu) has been undertaken by experimental investigations (SEM-EDX, DTA and XRD) and density functional theory (DFT) calculations. These compounds crystallize in the hexagonal Y3NiAl3Ge2-type structure (hP9, P–62m, Z = 1) (an ordered, quaternary derivative of the ternary ZrNiAl or of the binary Fe2P prototypes), with lattice parameters values a = 7.0239(2) Å and c = 4.2580(1) Å for Gd3MnAl3Ge2 and a = 7.0434(1) Å and c = 4.2089(1) Å for Gd3CuAl3Ge2. DTA suggests a peritectic reaction for the formation of these compounds (at 1245°C for Gd3CuAl3Ge2). The existence and stability of these phases has been explained on the basis of DFT calculations, and a comparison of ground state properties of the studied compounds with the earlier known Gd3CoAl3Ge2 phase is outlined. The negative formation energies in all three cases govern the stability of compounds from theory as well, predicting Gd3MnAl3Ge2 as the most stable phase with highest formation energy (–13.01 eV/f.u.). The total DOS are generic in nature and suggest the robust magnetism, with the Gd-f moments of ≈7 μB. An antiparallel coupling among Gd-f and T-d states is observed for all compounds, as usually seen in rare earth (R) - transition metal (T) compounds. Preliminary magnetization measurements on Gd3MnAl3Ge2 show two ferromagnetic/ferrimagnetic (FM/FIM) like transitions at TC1 = 142 K and TC2 = 97 K, with another anomaly seen at ≈15 K. Isothermal magnetization data show no hysteresis even at 5 K, and the magnetization does not saturate up to 50 kOe, further suggesting a possible FIM behavior

System performances of fiber optical parametric amplifiers

International audienceThe research field of fiber optical parametric amplifiers has steadily expanded over the last two decades as a host of all-optical signal processing techniques have been demonstrated in nonlinear optical fibers such as wavelength conversion, optical regeneration, optical switching, limiting, buffering, and sampling. This article reviews the system performances of theses parametric devices such as gain bandwidth, focuses on the main limitations and demonstrates efficient techniques for suppressing the

Complete experimental characterization of stimulated Brillouin scattering in photonic crystal fiber

International audienceWe provide a complete experimental characterization of stimulated Brillouin scattering in a 160 m long solid-core photonic crystal fiber, including threshold and spectrum measurements as well as positionresolved mapping of the Brillouin frequency shift. In particular, a three-fold increase of the Brillouin threshold power is observed, in excellent agree-ment with the spectrally-broadened Brillouin gain spectrum. Distributed measurements additionally reveal that the rise of the Brillouin threshold results from the broadband nature of the gain spectrum all along the fiber and is strongly influenced by strain. Our experiments confirm that these unique fibers can be exploited for the passive control or the suppression of Brillouin scattering